Literaturnachweis - Detailanzeige
| Autor/inn/en | Armstrong, Christopher; Burnham, Jennifer A. J.; Warminski, Edward E. |
|---|---|
| Titel | Combining Sustainable Synthesis of a Versatile Ruthenium Dihydride Complex with Structure Determination Using Group Theory and Spectroscopy |
| Quelle | In: Journal of Chemical Education, 94 (2017) 7, S.928-931 (4 Seiten)Infoseite zur Zeitschrift
PDF als Volltext |
| Zusatzinformation | ORCID (Burnham, Jennifer A. J.) |
| Sprache | englisch |
| Dokumenttyp | gedruckt; online; Zeitschriftenaufsatz |
| ISSN | 0021-9584 |
| DOI | 10.1021/acs.jchemed.6b00874 |
| Schlagwörter | Science Instruction; Undergraduate Study; College Science; Spectroscopy; Science Laboratories; Chemistry; Scientific Concepts; Science Experiments; Laboratory Experiments; Molecular Structure; Theories |
| Abstract | A good-yielding two-step synthesis of RuH[subscript 2](CO)(PPh[subscript 3])[subscript 3] using conventional or microwave-assisted reflux techniques is described for use in undergraduate teaching laboratories. RuH[subscript 2](CO)(PPh[subscript 3])[subscript 3] is synthesized from RuCl[subscript 3]·xH[subscript 2]O, PPh[subscript 3], and KOH in ethanol in two steps under an inert atmosphere or using a one-pot microwave-assisted reflux to reduce the reaction time to approximately 10 min. This makes this useful compound readily available within an undergraduate laboratory session via efficient and sustainable syntheses, enabling learning outcomes associated with air-sensitive synthesis and application of group theory and spectroscopy to structure determination to be achieved. (As Provided). |
| Anmerkungen | Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc |
| Erfasst von | ERIC (Education Resources Information Center), Washington, DC |
| Update | 2020/1/01 |
Literaturbeschaffung und Bestandsnachweise in Bibliotheken prüfen
Permalink als QR-Code
Inhalt auf sozialen Plattformen teilen (nur vorhanden, wenn Javascript eingeschaltet ist)
Teile diese Seite:
