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Autor/inn/enSmellie, Iain A.; Forgan, Ross S.; Brodie, Claire; Gavine, Jack S.; Harris, Leanne; Houston, Daniel; Hoyland, Andrew D.; McCaughan, Rory P.; Miller, Andrew J.; Wilson, Liam; Woodhall, Fiona M.
TitelSolvent Extraction of Copper: An Extractive Metallurgy Exercise for Undergraduate Teaching Laboratories
QuelleIn: Journal of Chemical Education, 93 (2016) 2, S.362-367 (6 Seiten)Infoseite zur Zeitschrift
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Spracheenglisch
Dokumenttypgedruckt; online; Zeitschriftenaufsatz
ISSN0021-9584
DOI10.1021/acs.jchemed.5b00688
SchlagwörterLeitfaden; Unterricht; Lehrer; Science Instruction; College Science; Undergraduate Study; Metallurgy; Science Laboratories; Chemistry; Science Experiments; Laboratory Experiments
AbstractA multidisciplinary experiment for advanced undergraduate students has been developed in the context of extractive metallurgy. The experiment serves as a model of an important modern industrial process that combines aspects of organic/inorganic synthesis and analysis. Students are tasked to prepare a salicylaldoxime ligand and samples of the corresponding copper and nickel complexes, before performing test extractions and UV-vis spectroscopic analysis. The oxime ligand demonstrates a clear preference for extraction of Cu[superscript 2+] in the presence of Ni[superscript 2+] from aqueous solution under the conditions described. It is also possible to demonstrate that the ligand can be recovered and reused. The experiment has successfully been employed in a final year project-based laboratory course involving small groups of students. (As Provided).
AnmerkungenDivision of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Erfasst vonERIC (Education Resources Information Center), Washington, DC
Update2020/1/01
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